Charlotte became one only by marriage; then the male-line descendants were born into it. However, I heard that they ceased to use the Bourbon title after the marriage in 1981 of the current sovereign, because the then-head (Duke Charles, ex-husband of Princess Irene of the Netherlands) did not approve the union.
I don't believe Grand Duke Henri's children or nieces and nephews through his brothers are styled as princes and princesses of Bourbon-Parma ...
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